Source: New Scientist |
In a way that can assist with the recycling of metals from batteries, scientists from the University of Lyon, France, have come up with the chemistry to capture carbon dioxide (CO2) from the air to extract the metals.
The process uses a mixture of polyamines which adsorb carbon dioxide readily. The scientists used carbon dioxide from the exhaust of an internal combustion engine to be fixated into a polyamine solution. As result, they gradually created a library of CO2 loadings and solvents to assist with the precipitation of different metals.
They demonstrated that these metals could be extracted: lanthanum (La), nickel (Ni) and cobalt (Co). This shows that the three metal constituents of the La2Ni9Co alloys used to manufacture the batteries of electric vehicles can be separated and recovered by successive CO2-induced selective precipitations.
This research shows that CO2 can be captured sustainably as opposed to the capture and storage of CO2 underground.
References:
- Captured carbon dioxide could be used to help recycle batteries. New Scientist, January 13, 2020.
-“Simultaneous CO2 capture and metal purification from waste streams using triple-level dynamic combinatorial chemistry.” By J Septavaux, et.al. Nature Chemistry, 2020: https://doi.org/10.1038/s41557-019-0388-5